It's a snap to create a usable TOC in Captivate 4. Simply create your project and then choose Project > Table of Contents. Select Show TOC and every slide in your project will be added to the TOC.
While that was easy, you might notice that the titles assigned to each slide by default (Slide 1, Slide 2, etc.) aren't very descriptive.

If you'd like to add a more descriptive Title to the slides on your TOC, close the TOC dialog box and show the Properties of a slide (you can right-click a slide and choose Properties).
On the Slide tab, type a descriptive title in the Label field and click OK.

Return to the Table of Contents, select Show TOC and… BAM… the Label you typed on the Slide tab does double-duty and appears as a Title on the TOC.

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